浓硫酸钠水溶液中的离子对          下载免费PDF全文

刘元会  房春晖 《盐湖研究》2005,13(4):42-46

不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。  相似文献   

Semi‐analytical solution to one‐dimensional consolidation for unsaturated soils with semi‐permeable drainage boundary under time‐dependent loading          下载免费PDF全文

L. Wang  D. A. Sun  A. F. Qin  Y. F. Xu 《国际地质力学数值与分析法杂志》2017,41(16):1636-1655

This paper presents semi‐analytical solutions to Fredlund and Hasan's one‐dimensional consolidation of unsaturated soils with semi‐permeable drainage boundary under time‐dependent loadings. Two variables are introduced to transform two coupled governing equations of pore‐water and pore‐air pressures into an equivalent set of partial differential equations, which are easily solved by the Laplace transform. The pore‐water pressure, pore‐air pressure and settlement are obtained in the Laplace domain. Crump's method is adopted to perform the inverse Laplace transform in order to obtain semi‐analytical solutions in time domain. It is shown that the present solutions are more general and have a good agreement with the existing solutions from literatures. Furthermore, the current solutions can also be degenerated into conventional solutions to one‐dimensional consolidation of unsaturated soils with homogeneous boundaries. Finally, several numerical examples are provided to illustrate consolidation behavior of unsaturated soils under four types of time‐dependent loadings, including instantaneous loading, ramp loading, exponential loading and sinusoidal loading. Parametric studies are illustrated by variations of pore‐air pressure, pore‐water pressure and settlement at different values of the ratio of air–water permeability coefficient, depth and loading parameters. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

呼图壁地区震源机制解及构造应力场特征分析   总被引：2，自引：0，他引：2  

李艳永  王成虎  杨佳佳 《大地测量与地球动力学》2018,38(12):1246-1250

基于新疆测震台网记录的数字地震波形，运用CAP方法测定呼图壁地区2010-01-15~2017-01-02共50次MS≥3.0地震的震源机制解，同时结合早期23次MS≥3.0地震的震源机制解数据，应用MSATSI软件反演研究区时空应力场。结果表明，研究区应力结构类型表现为逆断型，整个区域主压应力P轴近NNE向且倾角较小，说明整个呼图壁地区应力场以NNE向水平挤压作用为主要特征。从空间上看，东部的水平挤压作用更为显著；从时间上看，2010~2016年受到更为显著的NNE向应力场控制，反映了研究区在不同时段应力场的调整变化，但没有改变该区域最大主压应力轴呈NNE向的总体特征，说明整个呼图壁地区可能主要受一种较稳定的NNE向应力场控制。  相似文献   

The groundwater recharge regime of some slightly metamorphosed neoproterozoic sedimentary rocks: an application of natural environmental tracers          下载免费PDF全文

Sandow Mark Yidana  Eric Koffie 《水文研究》2014,28(7):3104-3117

Isotope data of precipitation and groundwater in parts of the Voltaian Basin in Northern Ghana were used to explain the groundwater recharge regime in the area. Groundwater recharge is an important parameter in the development of a decision support system for the management and efficient utilization of groundwater resources in the area. It is therefore important to establish the processes and sources of groundwater recharge. δ¹⁸O and δ²H data for local precipitation suggest enrichment relative to the Global Meteoric Water Line (GMWL) and indicate that precipitation takes place at a relative humidity less than 100%. The groundwater data plot on an evaporation line with a slope of 5, suggesting a high degree of evaporative enrichment of the precipitation in the process of vertical infiltration and percolation through the unsaturated zone into the saturated zone. This finding is consistent with the observation of high evapotranspiration rates in the area and ties in with the fact that significant clay fraction in the unsaturated zone limits vertical percolation and thus exposes the percolating rainwater to the effects of high temperatures and low humidities resulting in high evapotranspiration rates. Groundwater recharge estimates from the chloride mass balance, CMB, method suggest recharge in the range of 1.8–32% of the annual average precipitation in the form of rainfall. The highest rates are associated with areas where open wells encourage significant amount of groundwater recharge from precipitation in the area. In the northern parts of the study area, groundwater recharge is lower than 12%. The recharge so computed through the application of the CMB methodology takes on a spatial distribution akin to the converse of the spatial pattern of both δ¹⁸O and δ²H in the area. As such, the locations of the highest recharge are associated with the most depleted values of the two isotopes. This observation is consistent with the assertion that low vertical hydraulic conductivities slow down vertical percolation of precipitation down to the groundwater water. The percolating precipitation water thus gets enriched in the heavier isotopes through high evapotranspiration rates. At the same time, the amount of water that finally reaches the water table is considerably reduced. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Torsional dynamic response of a large‐diameter pipe pile in viscoelastic saturated soil     

Changjie Zheng  Hanlong Liu  Xuanming Ding  Yaru Lv 《国际地质力学数值与分析法杂志》2014,38(16):1724-1743

An analytical solution is developed in this paper to investigate the dynamic response of a large‐diameter end‐bearing pipe pile subjected to torsional loading in viscoelastic saturated soil. The wave propagation in saturated soil and pile are simulated by Biot's two‐phased linear theory and one‐dimensional elastic theory, respectively. The dynamic equilibrium equations of the outer soil, inner soil, and pile are established. The solutions for the outer and inner soils in frequency domain are obtained by Laplace transform technique and the separation of variables method. Then, the dynamic response of the pile is obtained on the basis of the perfect contacts between the pile and the outer soil as well as the inner soil. The results in this paper are compared with that of a solid pile in elastic saturated soil to verify the validity of the solution. Furthermore, the solution in this paper is compared with the classic plane strain solution to verify the solution further and check the accuracy of the plane strain solution. Numerical results are presented to analyze the vibration characteristics and illustrate the effect of the soil parameters and the geometry size of the pile on the complex impedance and velocity admittance of the pile head. Finally, the displacement of the soil at different depth and frequency is analyzed. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

An analytical solution for deforming twin‐parallel tunnels in an elastic half plane          下载免费PDF全文

Jinyang Fu  Junsheng Yang  Li Yan  Syed Muntazir Abbas 《国际地质力学数值与分析法杂志》2015,39(5):524-538

The interaction between twin‐parallel tunnels affects the tunnelling‐induced ground deformation, which may endanger the nearby structures. In this paper, an analytical solution is presented for problems in determining displacements and stresses around deforming twin‐parallel tunnels in an elastic half plane, on the basis of complex variable theory. As an example, a uniform radial displacement was assumed as the boundary condition for each of the two tunnels. Special attention was paid to the effects of tunnel depth and spacing between the two tunnels on the surface movement to gain deep insight into the effect of the interaction between twin‐parallel tunnels using the proposed analytical approach. It is revealed that the influence of twin tunnel interaction on surface movements diminishes with both the increase of the tunnel depth and the spacing between the two tunnels. The presented analytical solution manifests that, similar to most of the existing numerical results, the principle of superposition can be applied to determine ground deformation of twin‐parallel tunnels with a certain large depth and spacing; otherwise, the interaction effect between the two tunnels should be taken into account for predicting reliable ground movement. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Displacement analytical prediction of shallow tunnel based on unified displacement function under slope boundary     

Fanchao Kong  Dechun Lu  Xiuli Du  Chenpeng Shen 《国际地质力学数值与分析法杂志》2019,43(1):183-211

For slope condition of ground surface, the asymmetrical deformation about the vertical center line and the horizontal center line of the tunnel cross section can be formed. A unified displacement function expressed by the Fourier series is presented to express the asymmetrical deformation of the tunnel cross section. Five basic deformation modes corresponding to the expansion order 2 are a complete deformation mode to reflect deformation behaviors of the tunnel cross section under slope boundary. Such this complete displacement mode is implemented into the complex variable solution for analytically predicting tunneling-induced ground deformation under slope boundary. All of these analytical solutions are verified by good agreements of the comparison between the analytical solutions and finite element method results. A parameter study is carried out to investigate the influence of deformation modes of the tunnel cross section, geometrical conditions of the tunnel and the slope angle, and “Buoyancy effect” on the displacement field. Finally, the proposed method is consistent with measured data of the Hejie tunnel in China qualitatively. The presented solution can provide a simplified indication for evaluating the ground deformation under slope condition of ground surface.  相似文献   

融合三边测量和PDR的室内定位关键技术分析及应用     

陈鹏  廖明  刘武平  呙维  宋杨 《测绘通报》2019,(2):17-21

随着无线室内定位技术的发展，室内定位效果有了明显提升，但仅采用无线定位方法，定位点跳动频繁，定位效果较差，难以获取连续位置的准确定位。实际应用中不同的硬件平台也会影响具体定位方法的选择，通常需采用多种技术手段的组合以达到理想定位效果。本文基于微信公众平台的服务需要，提出了一种基于三边测量定位和步行者航位推算（PDR）融合的室内定位方法，通过地图信息匹配纠正定位结果，得到连续稳定的定位结果；并集成室内地图可视化技术，研发了一套基于微信平台的三维室内定位系统，在实际工程场景中进行应用，具有较好的定位效果。  相似文献   

A multidirectional semi‐analytical method for analysis of laterally loaded pile groups in multi‐layered elastic strata          下载免费PDF全文

F.S. Tehrani  M. Prezzi  R. Salgado 《国际地质力学数值与分析法杂志》2016,40(12):1730-1757

A semi‐analytical method for calculating the response of single piles and pile groups subjected to lateral loading is developed in this paper. Displacements anywhere in the soil domain are tied to the displacements of the piles through decay functions. The principle of virtual work and the calculus of variations are used to derive the governing differential equations that describe the response of the piles and soil. The eigenvalue method and the finite difference technique are used to solve the system of coupled differential equations for the piles and soil, respectively. The proposed method takes into account the soil surface displacement along and perpendicular to the loading direction and produces displacement fields that are very close to those produced by the finite element method but at lower computational effort. Compared with the previous method that considered only the soil displacement along the loading direction, accounting for the multi‐directional soil displacement field produces responses for the piles and soil that are closer to those approximated by the finite element method. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Groundwater mixing between different aquifer types in a complex structural setting discerned by elemental and stable isotope geochemistry          下载免费PDF全文

Dorina Murgulet  Marlon Cook  Valeriu Murgulet 《水文研究》2016,30(3):410-423

Karst aquifers are well known for their intricate stratigraphy and geologic structures, which make groundwater characterization challenging because flowpaths and recharge sources are complex and difficult to evaluate. Geochemical data, collected from ten closely spaced production wells constructed in two karst aquifers (Bangor Limestone (Mb) and Tuscumbia Limestone/Fort Payne Chert (Mftp)) in Trussville, north‐central Alabama, illustrate two distinctive groundwater end‐members: (1) higher major ion, dissolved inorganic carbon, conductivity, alkalinity concentrations, heavier δ¹³C ratios (max: −10.2 ± 0.2‰ Vienna Pee Dee Belemnite (PDB)) and lower residence times (mean: 19.5 ± 2 years, n = 2) of groundwater in the Mb aquifer and (2) lower constituent concentrations, lighter δ¹³C ratios (min: −13.4 ± 0.2‰ PDB) and longer residence times of groundwater (mean: 23.6 ± 2 years, n = 4) in the Mftp aquifer. Summer and fall data and the binary mixing model show aquifer inter‐flow mixing along solution fractures and confirms the distinctive groundwater geochemistry of the two aquifers. Lowering of static water levels over the summer (drawdown from 2 to 5.2 m) leads to more reducing groundwater conditions (lower Eh values) and slightly enriched δ¹⁸O and δD ratios during the fall [δ¹⁸O: −4.8 ± 0.1 to −5.4 ± 0.1‰ Vienna Standard Mean Oceanic Water (VSMOW), n = 9; δD: −25.4 ± 1 to −27.4 ± 1‰ VSMOW, n = 9] when compared with summer season samples (δ¹⁸O: −5.1 ± 0.1 to −5.7 ± 0.1‰ VSMOW, n = 11; δD: −25.0 ± 1 to −30.6 ± 1‰ VSMOW, n = 11). GIS analyses confirm the localized origin of recharge to the investigated aquifers. The combination of GIS, field parameters and geochemistry analyses can be successfully used to identify recharge sources, evaluate groundwater flow and transport pathways and to improve understanding of how groundwater withdrawals impact the sustainability and susceptibility to contamination of karst aquifers. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献